Preheat oven to 160 °C (320°F) with the fan on (see note 4 if you don't have a fan function) and grease and/or line two 8 inch cake tins (I use my homemade cake release). In a bowl, sift together your flour, cornflour, baking soda, baking powder and salt. Using a whisk or fork, mix until well combined. Set aside.
In another bowl, add in your butter, vegetable oil and sugar. Using an electric mixer (hand or stand mixer are both fine - see note 2), cream together for 2 minutes until light and creamy.
Add in eggs one by one, mixing well in between each addition (about 10-15 seconds between eggs).
Add in your vanilla, vinegar and half a cup of the buttermilk, and mix until well combined. Now set your mixer aside as the remainder of the batter will be finished by hand.
Finish off by adding in half of your premixed dry ingredients to your wet mixture, and gently fold it in with a spatula until just combined. Then add in the remaining 1 cup of buttermilk, and fold it in until just combined. Lastly, add in the remaining dry ingredients and gently fold it into the mixture until just combined. Do not overmix (see note 3).
Divide the batter equally into two separate bowls (I would recommend weighing the batter to make sure you have an even amount in each bowl. Mine comes to around 685g each once divided).
To one half of the batter, add in the cocoa powder, instant coffee powder and vegetable oil. Fold with a spatula until just combined.
Divide the batter evenly into the two 8 inch cake tins. You can use your own marbling technique or use the method I like to use which gives you a very cool pattern on the inside. To do this, place 3 tablespoons of the chocolate batter in the middle of each cake tin. Spread out a little and then directly on top of it add in 3 tablespoons of the vanilla cake batter. Repeat these steps alternating between the two flavours. Every now and then I like to gently shake/twirl the cake tin to help the batter spread out towards the edges of the cake tin (I would recommend watching the video below for a demonstration of this technique).
Once all the batter is used up, gently shake the tins again to help even out the batter, and gently tap them on your countertop twice to remove any large air bubbles.
OPTIONAL: If you won't be icing your cake, then you create a nice flower like pattern on the top of your cake. To do this, place a toothpick at the edge of the cake tin, and drag it into the middle of the cake tin and lift it out. Wipe the toothpick clean and then do the same thing on the opposite side of the cake tin. Now keep doing this, working your way around the cake tin (I do it 8 times in total). I would recommend watching the video demonstration below as it's a little hard to explain! :)
Bake for 35 minutes or until a toothpick comes out clean. Once done, let the cakes cool in the cake tins for 20 minutes and then turn them out onto a wire rack to completely cool before frosting with the whipped chocolate ganache or another frosting of your choice.